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Please use this identifier to cite or link to this item: http://gukir.inflibnet.ac.in:8080/jspui/handle/123456789/5623
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dc.contributor.authorBadiger B.M
dc.contributor.authorPatil S.A
dc.contributor.authorAngadi S.D
dc.contributor.authorKulkarni V.H.
dc.date.accessioned2020-06-12T15:08:22Z-
dc.date.available2020-06-12T15:08:22Z-
dc.date.issued1987
dc.identifier.citationJournal of The Less-Common Metals , Vol. 133 , 2 , p. 263 - 269en_US
dc.identifier.uri10.1016/0022-5088(87)90236-0
dc.identifier.urihttp://gukir.inflibnet.ac.in:8080/jspui/handle/123456789/5623-
dc.description.abstractOxotitanium(IV) complexes were prepared by treating oxotitanium(IV) perchlorate with thiocarbohydrazone in a methanolic medium. The complexes are orange-yellow in colour and have 1:1 stoichiometry of the type TiO · L. Titanium(IV) complexes were prepared by reacting titanium(IV) chloride (anhydrous) with thiocarbohydrazone in an anhydrous chloroform medium. These are reddish brown in colour and conform to a 1:1 stoichiometry of the type TiL · Cl2. L in both cases stands for a doubly deprotonated ligand. IR and proton magnetic resonance (PMR) spectral studies suggest that the oxotitanium(IV) complexes have a coordination number of five whereas titanium(IV) complexes have a coordination number of six. © 1987.en_US
dc.titleOxotitanium(IV) and titanium(IV) complexes with thiocarbohydrazonesen_US
dc.typeArticle
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