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Please use this identifier to cite or link to this item: http://gukir.inflibnet.ac.in:8080/jspui/handle/123456789/4867
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dc.contributor.authorSuresh, T
dc.contributor.authorKumar, SS
dc.contributor.authorKottureshawara, NM
dc.contributor.authorRevanasidappa, M
dc.contributor.authorKhasim, S
dc.contributor.authorSuresh
dc.date.accessioned2020-06-12T15:05:28Z-
dc.date.available2020-06-12T15:05:28Z-
dc.date.issued2008
dc.identifier.citationE-JOURNAL OF CHEMISTRY , Vol. 5 , 2 , p. 404 - 408en_US
dc.identifier.uri10.1155/2008/989205
dc.identifier.urihttp://gukir.inflibnet.ac.in:8080/jspui/handle/123456789/4867-
dc.description.abstractAdduct formation constants have been determined by spectrophotometric study of a few typical bases with nickel(II) chelate of 4-methyl-8-quinolinol in chloroform. Bathochromic and hypsochromic shifts were observed in the visible range due to the adduct formation. Monobasic bases like pyridine, methyl substituted anilines and such other bases exhibit 1: 2 stoichiometry giving hexa - coordinated adductds. The dibasic bases such as 1,10-phenanthroline and 2,9- neocuproine exhibit 1 : 1 stoichiometry giving hexacoordinated adducts. The experimental results are discussed in terms of the basicity and steric effects of the various bases.en_US
dc.publisherHINDAWI LTD
dc.subjectAdduct formation
dc.subjectSteric hindrance
dc.subjectFormation constant
dc.titleSpectrophotometric Study of Nitrogen Base Adducts of Nickel(II)-4-methyl-8-quinolinateen_US
dc.typeArticle
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